RSC Corday Morgan Award Lecture - Solar-driven Reforming of Waste Polymers for the Synthesis of Sustainable Fuels and Chemicals
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The synthesis of solar fuels and chemicals through artificial photosynthesis allows the direct pairing of light absorption to drive chemical redox processes. This approach is a one-step and versatile alternative to the more indirect coupling of a photovoltaic cell with electrolysis and enables potentially the synthesis of a wide range of fuels and feedstock chemicals. A common drawback in most artificial photosynthetic systems and organic photocatalysis is their reliance on expensive materials and device architectures, which challenges the development of ultimately scalable devices. Another limitation in many approaches is their inefficiency and reliance on sacrificial redox reagents, which may be system damaging and often prevent truly energy-storing chemistry to proceed. This presentation will give an overview about our recent progress in developing semiconductor suspension systems to perform efficient full redox cycle solar catalysis with inexpensive components, and our approach for sustainable waste polymer (biomass and plastics) photoreforming and fine chemical synthesis.
Representative recent publications
(1) “Electro- and solar-driven fuel synthesis with first row transition metal complexes”
Dalle, Warnan, Leung, Reuillard, Karmel, Reisner, Chem. Rev., 2019, 119, 1752.
(2) “Photoreforming of lignocellulose into H2 using nanoengineered carbon nitride under benign conditions”
Kasap, Achilleos, Huang, Reisner, J. Am. Chem. Soc., 2018, 140, 11604.
(3) “Plastic waste as a feedstock for solar-driven H2 generation”
Uekert, Kuehnel, Wakerley, Reisner, Energy Environ. Sci., 2018, 11, 2853.
(4) “Solar Hydrogen Generation from Lignocellulose”
Kuehnel, Reisner, Angew. Chem. Int. Ed., 2018, 57, 3290.
(5) “Solar-driven reforming of lignocellulose to H2 with a CdS/CdOx photocatalyst”
Wakerley, Kuehnel, Orchard, Ly, Rosser, Reisner, Nature Energy, 2017, 2, 17021.
(6) “Carbon dots as photosensitisers for solar-driven catalysis”
Hutton, Martindale, Reisner, Chem. Soc. Rev., 2017, 47, 6111.
(7) “Solar-driven Reduction of Protons Coupled to Alcohol Oxidation with a Carbon Nitride-Catalyst System”
Kasap, Caputo, Martindale, Godin, Lau, Lotsch, Durrant, Reisner, J. Am. Chem. Soc., 2016, 138, 9183.
Theatre C, Purdie
May 29, 2019
From: 14h00 To: 15h00
Royal Society of Chemistry